Bioplastics

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Contents

Introduction

Bioplastics are a relatively new addition to the plastics family and typically take two forms. "Hydrobiodegradables" are made from food or plant starch, yet often contain some percentage of synthetic (oil-based) polymers as well. Under certain conditions, these plastics can be broken down into water, carbon dioxide, methane, and biomass primarily through the enzymatic action of microorganisms. But for many brands, this can only occur within industrial composting conditions with their higher humidity and heat. "Oxobiodegradables", like traditional plastics, are often made exclusively from nonrenewable petroleum byproducts but have bio-additives included to help them break down faster – after a preset period of time. Exposure to such things as sunlight, heat, and mechanical stress ultimately can reduce oxobiodegradables to a mix of water, CO2, and biomass, making them suitable for composting.

Products on the market are made from a variety of natural feedstocks including corn, potatoes, rice, tapioca, palm fiber, wood cellulose, wheat fiber and bagasse. Products are available for a wide range of applications such as cups, bottles, cutlery, plates, bags, bedding, furnishings, carpets, film, textiles and packaging materials. In the US, the percentage of bio-based ingredients required for a product to be referred to as bio-based, is defined by the USDA on a product-by-product basis. The Institute for Local Self-Reliance has recommended that the USDA set a minimum threshold of 50 percent bio-based content for products to be considered bio-based.

An article Sustainability of bio-based plastics: general comparative analysis and recommendations for improvement by Clara Rosalía Álvarez-Chávez, Sally Edwards, Rafael Moure-Eraso and Kenneth Geiser was published in the Journal of Cleaner Production in 2012. While the article's abstract states:

"Bio-based plastics appear to be more environmentally friendly materials than their petroleum-based counterparts when their origin and biodegradability are compared."


It also states:

"Results of this qualitative study were displayed in two Bioplastics Spectrums that provide a visual summary of the data gathered on bio-based plastics according to sustainability criteria. This analysis found that none of bio-based plastics currently in commercial use or under development are fully sustainable. Each of the bio-based plastics reviewed utilizes: genetically modified organisms for feedstock manufacture and/or toxic chemicals in the production process or generates these as byproducts, and/or co-polymers from non-renewable resources."


Biodegradable and Compostable Claims

There are several manufacturers of plastic products that claim that their bottles or bags are "biodegradable" or "compostable." Here are some of these products and the manufacturer's claims, as reported and evaluated[1] by The Institute for Local Self Reliance:

  • The Biogreen Bottle™ reusable water bottle made from LDPE: “100% biodegradable, recyclable and reusable” “BioGreen Plastic will fully biodegrade in home compost heaps, commercial composting operations, buried in the ground, buried in landfills, tilled into the soil, having been littered etc. Most importantly, this process is by far the most widely applicable, proven technology for the biodegradation of plastics in the world.”
  • Aquamantra’s ENSO™ single-use water bottle made from PET: “Launches world’s first 100% biodegradable-recyclable bottle” “ENSO™ bottles are validated through third party ASTM standard tests.” “ENSO Bottles are 100% biodegradable and compostable” “Our PET bottles will biodegrade in anaerobic and aerobic/compostable environments”
  • Perf Go Green biodegradable plastic bags, including lawn and leaf bags: “Once Perf Go Green products are discarded (whether that be on land, underground, at sea, etc.) they will completely degrade and break down returning to nature in as little as 12-24 months – leaving absolutely NO residue or harmful toxins.” (Note that even if you believe these claims, a bag in the ocean would sill be there a minimum of 1 to 2 years).
  • PolyGreen polyethylene plastic newspaper bags by GP Plastics Corporation: “100% oxo-biodegradable” “Because they are conventional plastics with an additive, they are compatible with the existing recycle stream.”
  • Planet Green Bottle Corporation’s Reverte™ oxo-degradable PET plastic bottle: “The PGBC oxo-biodegradable PET plastic bottle is compatible with all current recycling streams for PET plastic bottles.” “Reverte™ does indeed firstly break down the PET into fragments but then these fragments are bio-digested until all that ultimately remains is CO2 and water.” “Reverte™ PET bottles will oxo-biodegrade if they find their way into the ocean since in this environment there is usually plenty of oxygen, UV light and heat which are required for the oxo-biodegradation process.”
  • Discover’s biodegradable PVC credit card: “The biodegradable Discover Card is made of biodegradable PVC, a substance that allows 99 percent of the card plastic to be safely absorbed when exposed to landfill conditions.”


Most if not all these claims are unsubstantiated. The companies selling these products are taking advantage of markets that are unaware of the difference between certifiable compostable and biodegradable products and those that are not. Truly biodegradable plastics are plastics that can decompose into carbon dioxide, methane, water, inorganic compounds, or biomass via microbial assimilation (the enzymatic action of microorganism). To be considered biodegradable, this decomposition has to be measured by standardized tests, and take place within a specified time period, which vary according to the “disposal” method chosen. The American Society of Testing and Materials (ASTM) has created definitions on what constitutes biodegradability in various disposal environments.

Steve Mojo of the Biodegradable Products Institute (BPI) has repeatedly asked to see Aquamantra’s claims that its PET will fully biodegrade in landfills or marine environments. “Nothing of credible science has come back.”[2] On oxo-degradables, Steve acknowledges these plastics can fragment within 3 months but clarifies that fragmentation is not a sign of biodegradation and that no data shows how long these plastic fragments will persist in the soil or the marine environment. According to Dr. Ramani Narayan, an international expert on biodegradability and a professor of Chemical Engineering & Materials Science at the Michigan State University, some evidence presented shows partial degradation but “the key phrase is ‘complete’ – if they are not completely utilized, then these degraded fragments, which may even be invisible to the naked eye, pose serious environmental consequences."[3]

Oxo-degradable plastics do not meet any standards in place for biodegradability and should not be considered biodegradable. In fact, the US National Advertising Division of the Council of Better Business Bureaus has recommended that GP Plastics Corporation modify or discontinue some of its advertising claims for its oxo-degradable PolyGreen bags. In California, a study sponsored by the California Integrated Waste Management Board (CIWMB) and led by Dr. Joseph Greene at California State University showed that oxo-degradable bags on the markets showed no biodegradation.[4] Its findings and the proliferation of unsupported biodegradability claims, led the state to pass two laws effective January 2009 that restrict use of the terms “compostable,” “biodegradable” “degradable,” and “marine degradable” on plastic bags.[5]

Plastic-bag-turtle-300x187.jpg



Do plastic bags (or even 'biodegradable' plastic bags) degrade while in the stomachs of sea turtles? A study by Müller, et al[6] published in December 2011 set out to test the decay characteristics of three common types of shopping bag polymers in sea turtle gastrointestinal fluids: standard and degradable plastic, and biodegradable. Degradation rates of the standard and the degradable plastic bags after 49 days across all treatments and controls were negligible. The biodegradable bags showed mass losses between 3% and 9%. This was a much slower rate than reported by the manufacturers in an industrial composting situation (100% in 49 days). The study concluded: "While the breakdown rate of biodegradable polymers in the intestinal fluids of sea turtles is greater than standard and degradable plastics, it is proposed that this is not rapid enough to prevent morbidity."

Bioplastics typically need the high heat (100 to 140 degrees F) of a composting process to truly biodegrade. These products typically act like conventional plastic and only 'photodegrade' (slowly disintegrate into ever smaller pieces while still retaining the basic polymer structure) when left in the park, on the beach or in the ocean. Proceed with caution. These products are a step in the right direction but not a full solution, it's best to reduce and reuse when possible before buying new products.

Conclusions

Substantial efforts are underway by polymer scientists to develop viable bioplastics. However, “None of the [current] alternatives are what they should be,” Daniella Russo, the Plastic Pollution Coalition’s executive director, says. “For an alternative plastic to succeed, it should be non-toxic over its entire life cycle, fully biodegradable in all situations, and cost competitive.”

Also keep in mind that although these products may be made from plant rather than petroleum raw materials, the basic chemical structure (PET, LDPE, PVC, etc.) of the plastic bag or bottle is still the same. Equally important to remember is that these bags or bottles are still single use plastics. Reusable bags, bottles or other containers are a much better alternative. Better for the ocean and better for your wallet.

Information Sources

About Bioplastics, Institute for Local Self-Reliance

Biodegradable Plastics: True or False? Good or Bad?, Institute for Local Self-Reliance

Facing the Dirty Truth About Recyclable Plastics, Yale University, Environment 360

A Primer on Biodegradable Plastics, Christian Science Monitor

Is New Biodegradable Plastic the Answer?, Treehugger

Bioplastics: Are They the Solution? Algalita Marine Research Institute

Footnotes

  1. http://www.sustainableplastics.org/spotlight/biodegradable-plastics-true-or-false-good-or-bad
  2. Mojo, Steve. “Re: biodegradability claims.” Message to Brenda Platt. 18 March. 2009. Email. Also see, BPI's comments on the use of additives in their fact sheet, Background on Biodegradable Additives.
  3. For a detailed technical review and rebuttal of biodegradability claims, see Dr. Ramani Narayan's, Biodegradability… Bioplastics Magazine [01/09, Vol. 4], pp. 28-31.
  4. See "Performance Evaluation of Environmentally Degradable Plastic Packaging and Disposable Service Ware," CIWMB Publication Number: 432-08-001, June 2007.
  5. For information on these laws, AB 7071 (Plastic Labeling Enforcement) and AB1972 (Truthful Environmental Advertising for Plastics), go to: http://www.cawrecycles.org/node/... and http://www.cawrecycles.org/issues/...
  6. Christin Müller, Kathy Townsend, Jörg Matschullat, Experimental degradation of polymer shopping bags (standard and degradable plastic, and biodegradable) in the gastrointestinal fluids of sea turtles, Elsevier, 2011.